Waterbased acrylic PSA adhesion strength refers to the force required to separate a water-based acrylic pressure sensitive adhesive from a substrate, a critical property that determines bonding reliability across applications such as packaging, labeling, and medical tapes. It is influenced by factors including adhesive formulation, substrate surface energy, application pressure, and environmental conditions (temperature, humidity). Adhesion strength is typically measured as peel strength (force per unit width, e.g., N/25mm) using standardized tests (ASTM D3359), with values ranging from low (1–5 N/25mm for removable labels) to high (15+ N/25mm for permanent bonding). To tailor adhesion strength, formulators adjust monomer composition: increasing the proportion of polar monomers (e.g., acrylic acid, hydroxyethyl acrylate) enhances adhesion to high-surface-energy substrates (metals, glass) by promoting chemical interactions (hydrogen bonding), while non-polar monomers (e.g., 2-ethylhexyl acrylate) improve adhesion to low-surface-energy substrates (plastics like PE, PP) through physical wetting. Tackifiers are added to increase surface tack, improving initial adhesion by enhancing wetting of the substrate. Polymer molecular weight and distribution play a role: higher molecular weights improve cohesion but may reduce wetting (lowering adhesion to rough substrates), while lower molecular weights enhance wetting but can reduce overall strength. Application parameters are also critical—applying sufficient pressure ensures intimate contact between the adhesive and substrate, maximizing van der Waals forces, while proper drying (removing residual water) ensures the adhesive forms a continuous film. Surface preparation (cleaning, corona treatment) increases substrate surface energy, improving wetting and adhesion. These factors allow formulators to customize adhesion strength for specific needs, from easy-to-remove labels to high-strength bonding in industrial applications, ensuring waterbased acrylic PSAs perform reliably across diverse substrates and conditions.